Photochemical preparation of 3-(organothio) aldehydes

B - Operations – Transporting – 01 – J

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204/91.2

B01J 19/12 (2006.01) C07C 319/18 (2006.01) C07C 323/22 (2006.01)

Patent

CA 2015355

ABSTRACT OF THE DISCLOSURE A process is disclosed for the preparation of 3- (organothio)aldehydes by reacting a mercaptan with an .alpha., .beta.-unsaturated aliphatic aldehyde under actinic radiation in the absence of an oxygen-containing gas wherein the mercaptan and aldehyde are mixed in substantially eguimolar amount and the reaction temperature ranges from about 2° to less than 60°C.

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