Integrated process for the production of reformate having...

C - Chemistry – Metallurgy – 10 – G

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C10G 69/08 (2006.01)

Patent

CA 2206309

An integrated process for providing a gasoline boiling range reformate- containing product produced from naphtha comprises: (1) pretreating a raw naphtha feedstream containing benzene by contacting with a hydrodesulfurization catalyst thereby forming H2S and thereafter cascading said feedstream over a noble metal-containing porous crystalline inorganic oxide catalyst comprising pores having openings of 12-member rings under conditions sufficient to effect benzene saturation, thereby providing a pretreated effluent of reduced benzene content; (2) dehexanizing the pretreated effluent to provide a C6-hydrocarbon-containing overhead stream and a bottoms stream containing C7+ hydrocarbons; (3) reforming said bottoms steam to form a reformate stream; and (4) combining said reformate stream and said C6-hydrocarbon-containing overhead steam to provide a combined gasoline boiling range product.

Procédé intégré d'obtention d'un produit contenant un réformât correspondant à la plage d'ébullition de l'essence consistant: (1) à prétraiter un courant d'alimentation de pétrole brut contenant du benzène en le mettant en contact avec un catalyseur d'hydrodésulfurisation de manière à obtenir du H¿2?S, puis à faire cascader ledit courant sur un catalyseur cristallin poreux d'oxyde minéral contenant un métal noble dont les pores présentent des ouvertures correspondant à des noyaux à 12 éléments, dans des conditions suffisantes pour saturer le benzène, ce qui fournit un effluent prétraité à teneur réduite en benzène; (2) à deshéxaniser l'effluent prétraité pour obtenir un courant de haut de colonne contenant des hydrocarbures C?6¿ et un courant de bas de colonne contenant des hydrocarbures C?7+¿; (3) à réformer lesdits courants de bas de colonne pour obtenir un courant de réformât; et à combiner ledit courant de réformât et le courant de haut de colonne contenant des hydrocarbures C?6¿ pour obtenir un produit combiné.

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