Bisacylphosphines

C - Chemistry – Metallurgy – 08 – L

Patent

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C08L 57/00 (2006.01) C07F 9/50 (2006.01) C08F 2/50 (2006.01) C08K 5/53 (2006.01) C09D 157/00 (2006.01) G03F 7/029 (2006.01)

Patent

CA 2059145

A-18495/A Bisacylphosphines Abstract of the Disclosure Bisacylphosphines of formula I Image wherein R1 is unsubstituted C1-C18alkyl or C1-C8alkyl which is substituted by phenyl, -CN, C1-C12alkoxy or halogen, C2-C18alkenyl, unsubstituted C5-C8cycloalkyl or C5-C8cycloalkyl which is substituted by C1-C12alkyl, C1-C12alkoxy or halogen, or a 5- or 6-membered aromatic heterocyclic radical which contains oxygen, sulfur andlor nitrogen and is unsubstituted or substituted by halogen, C1-C4alkyl or C1-C4alkoxy, and R2 and R3 are each independently of the other unsubstituted C1-C18alkyl or C1-C8alkyl which is substituted by phenyl, halogen or C1-C12alkoxy, C2-C6alkenyl, unsubstituted C5-C8cycloalkyl or C5-C8cycloalkyl which is substituted by C1-C12alkyl, C1-C12alkoxy or halogen, unsubstituted C6-C12aryl or C6-C12aryl which is substituted by C1-C12alkyl, C1-C12alkoxy, C2-C12alkoxyalkyl, C1-C4alkylthio or halogen, or a 5- or 6-membered aromatic heterocyclic radical which contains oxygen, sulfur and/or nitrogen and is unsubstituted or substituted by halogen, C1-C4alkyl or C1-C4alkoxy, can be used as photoinitiators for the photopolymerisation of compounds which contain ethylenically unsaturated double bonds.

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