Method of preparation of calcium-binding polycarboxy...

C - Chemistry – Metallurgy – 08 – B

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C08B 37/18 (2006.01) C08B 31/18 (2006.01) C08B 33/08 (2006.01) C11D 3/20 (2006.01) C11D 3/22 (2006.01)

Patent

CA 2081483

The invention provides a method for the preparation of a calcium-complexing polycarboxy compounds be oxidising inulin in the presence of a low concentration of hypohalite, resulting in the production of a polycarboxyinulin containing about 1.2-2.6 carboxyl groups per monosaccharide unit. The hypohalite is preferably hypobromite, which can be produced in situ by chemical or electrochemical oxidation of a catalytic amount of bromide. The polycarboxyinulin can be used as a phosphate substitute in calcium-binding agents and detergents.

L'invention se rapporte à un procédé, qui sert à préparer un composé polycarboxy formant complexe avec le calcium par oxydation d'inuline en présence d'une faible concentration d'hypohalite, ce qui permet de produire une polycarboxyinuline contenant environ 1,2 à 2,6 groupes carboxyle par unité de monosaccharide. L'hypohalite est de préférence de l'hypobromite, qui peut être produit in situ par oxydation chimique ou électrochimique d'une quantité catalytique de bromure. La polycarboxyinuline peut être utilisée comme substitut du phosphate dans des agents de liaison avec le calcium et dans des détergents.

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