Polyol blend for the preparation of open cell rigid...

C - Chemistry – Metallurgy – 08 – G

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C08G 18/63 (2006.01) C08G 18/40 (2006.01) C08G 18/50 (2006.01)

Patent

CA 2329070

Polyol blend comprising: (a) a polyol component having an average hydroxyl value of 150 to 850 mg KOH/g and (b) a polymer polyol comprising a polymer stably dispersed in a base polyol medium, which base polyol medium has an average primary hydroxyl content of less than 20 %. This polyol blend is suitably applied in a process for the preparation of open cell rigid polyurethane foams, wherein it is reacted with a polyisocyanate component in the presence of at least a catalyst, a foam stabilising agent and a blowing agent. The resulting open cell rigid polyurethane foam has a density of less than 50 kg/m3 and a closed cell content of less than 10 %, preferably of less than 5 % and can suitably be applied as heat insulating material.

Ce mélange de polyols est constitué (a) d'un composant polyol présentant une valeur hydroxyle moyenne de 150 à 850 mg KOH/g, et d'autre part (b) d'un polyol polymère comprenant un polymère en dispersion stable dans un milieu polyol de base, lequel milieu polyol de base présente une teneur primaire moyenne en hydroxyle inférieure à 20 %. Ce mélange de polyols est appliqué de façon appropriée dans un processus de préparation de mousses de polyuréthane rigides à cellules ouvertes. En l'occurrence, on le fait réagir avec un polyisocyanate en présence d'au moins un catalyseur, d'un stabilisant de mousse et d'un agent d'expansion. La mousse de polyurétane rigide à cellules ouvertes obtenue présente une densité inférieure à 50 kg/m?3¿ et une proportion de cellules fermées inférieure à 10 %, de préférence inférieure à 5 %. Cette mousse convient comme matériau d'isolation thermique.

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