Fungicide mixture

A - Human Necessities – 01 – N

Patent

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A01N 47/24 (2006.01) A01N 37/50 (2006.01) A01N 37/52 (2006.01) A01N 43/50 (2006.01) A01N 43/54 (2006.01) A01N 43/653 (2006.01) A01N 55/10 (2006.01)

Patent

CA 2252677

\ This invention concerns a fungicide mixture containing in synergistically effective quantities a) a Carbamat of formula (I) in which T stands for CH or N, n for 0, 1 or 2, and R stands for halogen, C1C4-alkyl or C1C4-alkyl halide, where the radicals R can be different, if n stands for 2, and at least on compound is selected from b) oxime ethers of formula (II) (in which the substituents have the following meaning: X is oxygen or amino (NH); Y is CH or N; Z is oxygen, sulphur, amino (NH) or C1C4-alkyl amino (N-alkyl); R' is alkyl, alkyl halide, alkenyl, alkenyl halide, alkinyl halide, alkinyl, cycloalkyl-methyl or optionally substituted) benzyl, c.1) oxime ether carboxylic ester of formula (IIIa), c.2) oxime ether carboxylic acid amide of formula (IIIb), c.3) methoxyacrylic acid ester of formula (IIIc), d) one or more azole derivatives 1-[(2RS,4RS;2RS,4SR)-4-bromo- 2-(2,4-dichlorophenyl)tetrahydrofuryl]-1H-1,2,4-triazole (IV.1), 2-(4-chlorphenyl)-3-cyclopropyl-1-(1H-1,2,4-triazole-1-yl)-butan-2-of (IV.2), (+)-4-chloro-4-[4-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)-1,3- dioxolan-2-yl]-phenyl-4-chlorophenylehter (IV.3), (E)-(R,S)-1-(2,4- dichlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol (IV.4), (Z)-2-(1H-1,2,4-triazol-1-ylmethyl)-2-(4-fluorophenyl)-3-(2- chlorophenyl)-oxirane (IV.5), 4-(4-chlorophenyl)-2-phenyl- 2-(1H-1,2,4-triazolylmethyl)-butyronitril (IV.6), 3-(2,4-dichlorophenyl)-6- fluoro-2-(1H-1,2,4-triazolyl-1-yl)chinazolin-4(3H)-one (IV.7), bis(4-fluorophenyl)(methyl)(1H-1,2,4-triazol-1-yl-methyl)silane (IV.8), (R,S)-2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1- yl)-hexan-2-ol (IV.9), (1RS,5RS;1RS,5SR)-5-(4-chlorobenzyl)-2,2-dimethyl-1-(1H- 1,2,4-triazol-1-ylmethyl)cyclopentanol (IV.10), N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]imidazol-1-carboxamide (IV.11) (+)- 1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan- 2-yl-methyl-1H1,2,4-triazol (IV.12), (R,S)-1-(4-chlorophenyl)-4,4-dimethyl-3- (1H-1,2,4-triazol-1-ylmethyl)-pentan-3-ol (IV.13), (+)-2-(2,4-dichlorophenyl)-3-(1H-1,2,4-triazol-yl)-propyl-1-1,2,2- tetrafluorethylether (IV.14) and (E)-1-[1-[[4-chloro-2-(trifluoromethyl)- phenyl]imino]-2-propoxyethyl]-1H-imidazol (IV.15), (RS)-2,4'-difluoro-a-(1H- 1,2,4-triazol-1-ylmethyl)-benzhydryl-alcohol (IV.16), 2-p-chlorophenyl-2-(1H-1,2,4-triazol-1-ylmethyl)-hexane-nitrile (IV.17).

L'invention concerne un mélange fongicide contenant dans des quantités à effet synergique: a) un carbamate de la formule (I) dans laquelle T désigne CH ou N, n vaut 0, 1 ou 2 et R désigne halogène, alkyle ou halogénure d'alkyle, les restes R pouvant être différents lorsque n vaut 2, ainsi qu'au moins un composé sélectionné parmi b) des éthers d'oxime de la formule (II) (dans laquelle les substituants ont la signification suivante: X désigne oxygène ou amino (NH); Y désigne CH ou N; Z désigne oxygène, soufre, amino (NH) ou C1-C4 alkylamino(N-alkyle); R' désigne alkyle, halogénure d'alkyle, alcényle, halogénure alcényle, alcinyle, halogénure alcinyle, cycloalkylméthyle, ou benzyle éventuellement substitués), c.1) l'ester d'acide carboxylique d'éther d'oxime de la formule (IIIa), c.2) l'amide d'acide carboxylique d'éther d'oxime de la formule (IIIb), c.3) l'ester d'acide méthoxyacrylique de la formule (IIIc), d) un ou plusieurs dérivés pyrrole 1-[(2RS,4RS;2RS,4SR)-4-bromo-2-(2,4-dichlorophényl)tétrahydrofuryl]-1H-1,2,4-triazol (IV.1), 2-(4-chlorophényl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)-butan-2-ol(IV.2), (+)-4-chloro-4-[4-méthyl-2-(1H-1,2,4-triazol-1-ylméthyl)-1,3-dioxolan-2-yl]-phényl-4-chlorophényléther (IV.3), (E)-(R,S)-1-(2,4-dichlorophényl)-4,4-diméthyl-2-(1H-1,2,4-triazol-1-yl)pent-1-én-3-ol (IV.4), (Z)-2-(1H-1,2,4-triazol-1-ylméthyl)-2-(4-fluorophényl)-3-(2-chlorophényl)-oxirane (IV.5), 4-(4-chlorophényl)-2-phényl-2-(1H-1,2,4-triazolylméthyl)-butyronitrile (IV.6), 3-(2,4-dichlorophényl)-6-fluoro-2-(1H-1,2,4-triazol-1-yl)quinazolin-4-(3H)-one (IV.7), bis(4-fluorophényl)(méthyl)(1H-1,2,4-triazol-1-yl-méthyl)silane (IV.8), (R,S)-2-(2,4-dichlorophényl)-1-(1H-1,2,4-triazol-1-yl)-hexan-2-ol (IV.9), (1RS,5RS;1RS,5SR)-5-(4-chlorobenzyl)-2,2-dimenthyl-1-(1H-1,2,4-triazol-1-ylméthyl)cyclopentanol (IV.10), N-propyl-N-[2-(2,4,6-trichlorophénoxy)éthyl]imidazol-1-carboxamide (IV.11), (+)-1-[2-(2,4-dichlorophényl)-4-propyl-1,3-dioxolane-2-ylméthyle]-1H-1,2,4-triazol (IV.12), (R,S)-1-(4-chlorophényl)-4,4-diméthyl-3-(1H-1,2,4-triazol-1-ylméthyl)-pentan-3-ol (IV.13), (+)-2-(2,4-dichlorophényl)-3-(1H-1,2,4-triazol-yl)-propyl-1,1,2,2-tétrafluoroéthyléther (IV.14) et (E)-1-[1-[[4-chloro-2-(trifluorométhyle)-phényl]imino]-2-proproxyéthyle]-1H-imidazol (IV.15), (RS)-2,4'-difluoro- alpha -(1H-1,2,4-triazol-1-ylméthyl)-benzhydryle-alcool (IV.16), 2-p-chlorophényl-2-(1H-1,2,4-triazol-1-ylméthyl)-hexanenitrile (IV.17).

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