Carbamoylphenylsulfonylureas, processes for their...

C - Chemistry – Metallurgy – 07 – D

Patent

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C07D 239/52 (2006.01) A01N 47/36 (2006.01) C07C 309/86 (2006.01) C07C 311/15 (2006.01) C07C 311/16 (2006.01) C07C 311/54 (2006.01) C07D 239/42 (2006.01) C07D 239/46 (2006.01) C07D 239/47 (2006.01) C07D 239/56 (2006.01) C07D 251/16 (2006.01) C07D 251/22 (2006.01) C07D 251/46 (2006.01) C07D 251/52 (2006.01) C07D 275/06 (2006.01) C07D 521/00 (2006.01)

Patent

CA 2309438

The invention relates to compounds of formula (I) or the salts thereof, wherein R1, R3 = H, (substituted) hydrocarbon radical (KW) or (substituted) heterocyclyl, which comprise inclusive substituents 1-30 C-atoms, R2 = R0-Q0-, wherein R0 = H, (substituted) KW or (substituted) heterocyclyl radical, each inclusive substituents with 1-30 C-atoms and Q0 = direct binding or -O-, -SO2, -NH-, -N[(C1-C6)alkyl]-, -CO-, -CO-NH- or -O-CO-NH-; R4 = H, halogen, NO2, CN, (C1-C4)alkyl, (C1-C4)alkoxyl, [(C1-C4)alkyl]-carbonyl or [(C1-C4)alkoxyl] carbonyl, whereby each of the remaining 4 radicals can be halogenated; R5 = H or (C1-C4)alkyl; Q = O or NR*; R* = H, (C1-C4)alkyl, (C3-C4)alkenyl or (C3- C4)alkynyl, whereby each of the 3 remaining radicals can be substituted by halogen, (C1-C4)alkoxyl and/or (C1-C4)alkylthio, W = O or S; X, Y = H, halogen, (C1-C4)alkyl, (C1-C4)alkoxyl, (C1-C4)alkylthio, whereby each of the 3 remaining radicals can be substituted by halogen, (C1-C4)alkoxyl and/or (C1- C4)alkylthio, or mono- or di[((C1-C4)alkyl]-amino (C3-C4)cycloalkyl, (C2- C5)alkenyl, (C2-C5)alkynyl, (C2-C5)alkenyloxyl or (C2-C5)alkynyloxyl, Z = CH or N. The inventive compounds are suitable as herbicides or plant growth regulators, for example, for combating harmful plants in crop plants, also transgenic crop plants. Using the method, the compounds can be produced in accordance with claim 6 by partially novel intermediate products (c.f. compounds (II)* and (IX)' in accordance with claims 12 and 13).

L'invention concerne des composés de la formule (I) ou leurs sels. Dans la formule (I), R?1¿, R?3¿ = H, un reste hydrocarbure (KW) (subst.) ou un hétérocyclyle (subst.), qui possèdent des substituants inclusifs de 1-30 atomes de carbone; R?2¿ = R?0¿-Q?0¿-, où R?0¿ = H, KW (subst.) ou un reste hétérocyclyle (subst.), chacun ayant des substituants inclusifs de 1-30 atomes de carbone et Q?0¿ = une liaison directe ou -O-, -SO¿2?-, -NH-, -N[(alkyle (C¿1?-C¿6?))]-, -CO-, -CO-NH- ou -O-CO-NH-; R?4¿ = H, halogène, NO¿2?, CN, alkyle (C¿1?-C¿4?), alcoxy (C¿1?-C¿4?), [(alkyle (C¿1?-C¿4?))]-carbonyle ou [(alcoxy(C¿1?-C¿4?)]carbonyle, chacun des 4 derniers restes pouvant être halogéné; R?5¿ = H ou alkyle (C1-C4); Q = O ou NR*, R* = H, alkyle (C¿1?-C¿4?), alcényle (C¿3?-C¿4?) ou alkinyle (C¿3?-C¿4?), chacun des 3 derniers restes pouvant être substitué par un halogène, alcoxy (C¿1?-C¿4?) et/ou alkylthio (C¿1?-C¿4?), W= O ou S; X, Y = H, halogène, alkyle (C¿1?-C¿4?), alcoxy (C¿1?-C¿4?), alkylthio (C¿1?-C¿4?), chacun des 3 derniers restes pouvant être substitué par un halogène, alcoxy (C¿1?-C¿4?) et/ou alkylthio (C¿1?-C¿4?), ou mono- ou di((alkyle(C¿1?-C¿4?)-amino, cycloalkyle (C¿3?-C¿4?), alcényle (C¿2?-C¿5?), alkinyle (C¿2?-C¿5?), alcényloxy (C¿2?-C¿5?) ou alkinyloxy (C¿2?-C¿5?), Z = CH ou N. Ces composés conviennent particulièrement comme herbicides ou régulateurs de croissance des plantes, par exemple, dans la lutte contre les nuisibles des plantes cultivées, même des plantes cultivées transgéniques. Ils peuvent être produits selon le procédé conformément à la 6ème revendication concernant notamment de nouveaux produits intermédiaires (voir composés (II)* et (IX)' selon les 12ème et 13ème revendications).

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