Synthesis of hydrogeno-perfluoroalkanes

C - Chemistry – Metallurgy – 07 – C

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C07C 17/00 (2006.01) C07C 17/23 (2006.01) C07C 19/08 (2006.01)

Patent

CA 2060977

L'invention concerne la synthèse des hydrogéno- perfluoroalcanes RFH, RF désignant un radical perfluoroalkyle contenant 2 à 20 atomes de carbone, par réaction du iodure de perfluoroalkyle RFI correspondant avec un hydroxyde alcalin. L'emploi du méthanol comme solvant permet d'éviter la formation de goudrons, d'obtenir une conversion quasi- totale du RFI et un RFH d'excellente pureté, et de récupérer facilement l'iodure alcalin sous-produit.

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