Conversion of hydrofluorochloropropanes to fluoropropenes

C - Chemistry – Metallurgy – 07 – C

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C07C 17/35 (2006.01) C07C 21/18 (2006.01)

Patent

CA 2736437

Described is a method for producing fluoropropenes of formula CF3CX=CX2 wherein each X is F or H, at least one X is H, and at least one X is F, comprising pyrolyzing a hydrofluorochloropropane of formula CF3CXYCX2Y, wherein each X is F or H, at least one X is H, and at least one X is F, and one Y is Cl and the other Y is H, in the gas-phase in a reaction vessel, maintained at a temperature high enough to effect the pyrolysis of said hydrofluorochloropropane to said fluoropropene, wherein the selectivity for the production of the fluoropropene is at least 80%, in the absence of a catalyst

La présente invention concerne un procédé de préparation dun fluoropropylène de formule CF3CX=CX2 dans laquelle chaque X représente F ou H, au moins un X représentant H et au moins un X représentant F, qui consiste à pyrolyser un hydrofluorochloropropane de formule CF3CXYCX2Y dans laquelle chaque X représente F ou H, au moins un X représentant H et au moins un X représentant F, et un Y représente Cl et lautre Y représente H, en phase gazeuse dans un réacteur maintenu à une température suffisante pour effectuer la pyrolyse dudit hydrofluorochloropropane en fluoropropylène, avec une sélectivité en fluoropropylène dau moins 80 %, en l'absence de catalyseur.

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