Poly(ethylene oxalate), product formed or molded therefrom...

C - Chemistry – Metallurgy – 08 – G

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C08G 63/16 (2006.01) B29C 45/00 (2006.01) B29C 55/02 (2006.01) C08G 63/08 (2006.01) C08G 63/60 (2006.01) C08G 63/78 (2006.01) C08J 5/18 (2006.01) D01F 6/62 (2006.01)

Patent

CA 2179219

- 71 - The invention provides poly(ethylene oxalate) containing recurring units represented by the following formula (1): Image (1) in a proportion of at least 60 basal mol%, wherein (a) the solution viscosity (?inh) is at least 0.25 dl/g as measured at 30°C and a polymer concentration of 0.40 g/dl in a 4:1 (by weight) mixed solvent of m- chlorophenol and 1,2,4-trichloro-benzene, (b) the melt viscosity (?*) is at least 30 Pas as measured at 190°C and a shear rate of 1,000/sec, and (c) the density is at least 1.48 g/cm3 as measured in an amorphous state, various products formed or molded from the poly(ethylene oxalate) and a production process of the poly(ethylene oxalate) The polymer is high-molecular weight and excellent in melt processability, heat resistance, crystalline properties, mechanical properties and the like, and has good degradability in soil.

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