Process and apparatus for the selective partial oxidation of...

C - Chemistry – Metallurgy – 01 – B

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C01B 17/16 (2006.01)

Patent

CA 2617259

A process for purifying a light hydrocarbon stream containing H2S is disclosed in which the selective catalytic partial oxidation of the H2S component is carried out while the hydrocarbon components slip through substantially unconverted. A catalyst that favors the partial oxidation of H2S over conversion of the hydrocarbon component of a gaseous H2S-light hydrocarbon mixture is employed. Apparatus for selectively cleaning up light hydrocarbon streams containing low concentrations (e.g., less than 25 vol.%), and apparatus for selectively cleaning up light hydrocarbon streams having higher concentrations (e.g., greater than 25 vol.%) of H2S are also disclosed.

La présente invention se rapporte à un procédé de purification d'un flux d'hydrocarbures légers contenant du H2S, qui consiste en l'oxydation partielle catalytique sélective de l'élément H2S sensiblement sans conversion des éléments hydrocarbures. L'on utilise un catalyseur qui favorise l'oxydation partielle de H2S par rapport à la conversion des éléments hydrocarbures d'un mélange hydrocarbures légers-H2S. L'invention a également trait à un appareil permettant de nettoyer sélectivement des flux d'hydrocarbures légers à faible concentration de H2S (par ex., inférieure à 25 % vol.), et à un appareil permettant de nettoyer sélectivement des flux d'hydrocarbures légers à forte concentration de H2S (par ex., supérieure à 25 % vol.).

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