Production of pentafluoroethane

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 19/08 (2006.01) C07C 17/20 (2006.01) C07C 17/21 (2006.01) C07C 49/08 (2006.01)

Patent

CA 2184981

A process for the production of pentafluoroethane which comprises contacting a hydrofluorochloroethane having the formula: C2H1Cl1+xF1+y wherein x and y are each independently 0, 1, 2 or 3 provided that x + y is 3, with hydrogen fluoride in the vapour phase and in the presence of a fluorination catalyst which comprises zinc or a compound of zinc and chromia, chromium fluoride or chromium oxyfluoride. This may be one step of a two-step process in which the hydrochlorofluoroethane is produced by contacting perchloroethylene with hydrogen fluoride in the vapour phase over the same or a different fluorination catalyst.

Procédé de production de pentafluoroéthane consistant à mettre en contact un hydrofluorochloroéthane possédant la formule C¿2?H¿1?Cl¿1+x?F¿1+y? dans laquelle x et y valent chacun indépendamment 0, 1, 2 ou 3 à condition que x + y égalent 3, avec un fluorure d'hydrogène dans la phase vapeur et en présence d'un catalyseur de fluoruration comprenant du zinc ou un composé de zinc et de chromes, de fluorure de chrome ou d'oxyfluorure de chrome. Cette étape peut faire partie d'un procédé à deux étapes dans lequel on produit de l'hydrochlorofluoroéthane en mettant en contact du perchloroéthylène avec du fluorure d'hydrogène dans la phase vapeur sur un catalyseur de fluoruration identique ou différent.

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