Process for the preparation of a particularly pure...

C - Chemistry – Metallurgy – 07 – C

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C07C 53/16 (2006.01) C07C 51/43 (2006.01) C07C 51/487 (2006.01)

Patent

CA 2192536

The present invention relates to a process for the preparation of a particularly pure monochloroacetic acid, in which, in a first step, a hydrogenation of a mixture of mono- and dichloroacetic acid is carried out to a residual content of dichloroacetic acid of 400 to 600 ppm and, in a second step, this mixture is subjected to melt crystallization. The hydrogenation is carried out with a heterogeneous catalyst which comprises 0.1 - 5.0% by weight of palladium and in which active charcoal or silicon dioxide is used as the support.

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