Process for the preparation of high activity hydrocarbon...

B - Operations – Transporting – 01 – J

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252/63, 260/678.

B01J 37/02 (2006.01) B01J 23/74 (2006.01) B01J 23/75 (2006.01) C07C 1/04 (2006.01)

Patent

CA 2285032

A process for the preparation of a catalyst which is highly active for the synthesis of hydrocarbons from mixtures of hydrogen and carbon monoxide. A silica or silica-containing support is treated with a solution containing both an Iron Group metal, or metals, and nitrous acid, nitric acid, or a nitro-containing organo, or nitro-containing hydrocarbyl compound, or compounds, sufficient to hydroxylate the surface thereof and increase the number of hydroxyl groups on the surface of the support such that the metal component will be highly dispersed, this increasing the activity of the catalyst in a hydrocarbon synthesis reaction as contrasted with that of a catalyst of similar composition, similarly prepared except that the support component of the catalyst was not contacted and simultaneously treated with both the Iron Group metal and the acid.

La présente invention concerne l'élaboration d'un catalyseur hautement actif pour la synthèse d'hydrocarbures à partir de mélanges d'hydrogène et de monoxyde de carbone. Le procédé consiste à traiter un support en silice, ou chargé de silice, avec une solution contenant au moins un métal du Groupe du Fer, et, soit de l'acide nitreux ou nitrique, soit au moins un composé organo-nitré ou hydrocarbyle nitré, en quantité suffisante pour hydroxyler la surface du support et augmenter le nombre de groupes hydroxyles à la surface du support de façon que le composant métal se disperse fortement, augmentant ainsi l'activité du catalyseur pour la réaction de synthèse de l'hydrocarbure par rapport à l'activité d'un catalyseur de composition similaire, élaboré de façon similaire, à cette différence près que le composant support du catalyseur n'a pas été mis en contact, ni avec le métal du Groupe du Fer ni avec l'acide, et simultanément ainsi traité.

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