Process for preparing high crystallinity oxide thin film

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H01L 39/24 (2006.01) C23C 14/00 (2006.01) C23C 14/08 (2006.01) C30B 23/02 (2006.01)

Patent

CA 2152718

A process for preparing an oxide superconductor thin film which has a high crystallinity, clean and excellent superconductive surface on a substrate by reactive co-evaporation. The reactive co-evaporation process comprises the steps of evacuating the vacuum chamber to a pressure of 1 x 10-9 torr or lower, supplying an oxidizing gas selected from the group consisting of O2 including not less than 5 volume percent O3, pure N2O and pure NO2 so that a pressure in the proximity of the substrate becomes 6 x 10-6 to 8 x 10-5 Torr while a pressure in the proximity of the evaporation source becomes 1 x 10-9 Torr or lower, heating the substrate, and emitting a molecular beam onto the heated substrate so that the molecular beam is oxidized on and near the substrate and an oxide superconductor film is deposited on the substrate.

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