Solution catalyst having a bulky nitrogen ligand

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

C08F 10/02 (2006.01) C08F 2/06 (2006.01) C08F 4/643 (2006.01) C08F 110/02 (2006.01) C08F 4/659 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2225708

An easily synthesized catalyst for medium pressure solution polymerization is an unbridged, group 4 metal complex having a non-bulky cyclopentadienyl ligand and a very bulky nitrogen ligand. The simple and robust catalyst provides high molecular weight polymer under high temperature solution polymerization conditions. The catalyst must be activated with an ionic-type activator as it is not active when used with a conventional alumoxane activator.

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