Conversion of oxygenated organic compounds to fluorocarbons...

C - Chemistry – Metallurgy – 07 – C

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C07C 19/08 (2006.01) C07B 39/00 (2006.01) C07C 17/06 (2006.01) C07C 17/093 (2006.01) C07C 17/16 (2006.01) C07C 17/18 (2006.01) C07C 22/08 (2006.01) C07C 23/10 (2006.01)

Patent

CA 2203543

A method of fluorination by reacting UF6 with a C2 to C8 alcohol, acids, esters, aldehydes or epoxides. The preferred reagent is a monohydroxyl or polyhydroxyl alcohol which does not form a chelate when reacted with UF6. The reaction is conducted in the presence of a fluorination catalyst in an amount sufficient to catalyze the reaction between the UF6 and the alcohol, acids, esters, aldehydes or epoxides.

La présente invention concerne un procédé de fluoration consistant à faire réagir de l'hexafluorure d'uranium (UF¿6?) avec des acides, des esters, des aldéhydes, des époxydes ou un alcool C¿2? à C¿8?. Le réactif préféré est un alcool monohydroxyle ou polyhydroxyle qui ne forme pas de chélate lorsqu'il est mis en réaction avec l'hexafluorure d'uranium (UF¿6?). La réaction est effectuée en présence d'un catalyseur de fluoration en quantité suffisante pour catalyser la réaction entre l'hexafluorure d'uranium (UF¿6?) et l'alcool, les acides, les esters, les aldéhydes ou les époxydes.

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