Preparation of expandable thermoplastic polymers by...

C - Chemistry – Metallurgy – 08 – J

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C08J 9/12 (2006.01) C08J 9/18 (2006.01) C08K 3/32 (2006.01) C08K 13/02 (2006.01)

Patent

CA 2097008

Abstract of the Disclosure: A process for the preparation of expandable thermoplastic polymers by post-impregnation with a blowing agent in aqueous suspension in the pre- sence of a mixture of magnesium pyrophosphate and a sulfonate group-containing extender as suspension stabi- lizer, in a reactor comprises a) preparing the magnesium pyrophosphate in the same reactor at below 50°C by adding a solid magnesium salt in an amount corresponding to an at least 3% stoichiometric excess, based on pyrophosphate, to an aqueous solution of the pyrophosphate, b) heating the suspension medium to from 70 to 140°C and c) adding the blowing agent in this temperature range.

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