Dioxaspiroketal derivatives, process for their preparation...

C - Chemistry – Metallurgy – 07 – D

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Details

C07D 407/04 (2006.01) A61K 31/35 (2006.01) A61P 35/00 (2006.01) C07D 493/10 (2006.01)

Patent

CA 2652705

The invention relates to dioxaspiroketal derivatives of formula (I): wherein R, is selected from the group consisting of H, straight or branched chain C1-C6 alkyl, C1-C6 alkoxy, C2-C6 alkenyl, cycloalkyl, heterocyclyl, phenyl, optionally para-, meta- or ortho-substituted with 0 to 3 substituent selected from halogen, -CN, -NH2, -OH, -NO2, COOR2, wherein R2 is selected from H and C1-C6 alkyl, n is 1 or 2, X is O or S, R1 is selected from H, OH, halogen, C1-C6 alkyl, C1-C6 alkoxy, COOR3, wherein R3 is selected from H and C1-C6 alkyl, or physiologically acceptable salts thereof, process for preparation thereof, their uses in medical field, in particular as anti-tumour medicaments.

L'invention concerne des dérivés de dioxaspirocétal représentés par la formule (I), dans laquelle R est choisi dans le groupe comprenant H, alkyle C1-C6 à chaîne droite ou ramifiée, alcoxy C1-C6, alcényle C2-C6, cycloalkyle, hétérocyclyle, phényle, éventuellement substitué en para, méta ou ortho par 0 à 3 substituants choisis parmi halogène, -CN, -NH2, -OH, -NO2, COOR2, R2 étant choisi parmi H et alkyle C1-C6, n est égal à 1 ou 2, X représente O ou S, R1 est choisi parmi H, OH, halogène, alkyle C1-C6, alcoxy C1-C6, COOR3, R3 étant choisi parmi H et alkyle C1-C6, ou des sels physiologiquement acceptables de ceux-ci. L'invention concerne également un procédé de préparation de ces dérivés, ainsi que leurs utilisations dans le domaine médical, en particulier comme médicaments antitumoraux.

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