Synthesis of swainsonine and analogs thereof

Details Synthesis of swainsonine and analogs thereof Synthesis of swainsonine and analogs thereof

C - Chemistry, Metallurgy

07

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260/299, 260/323

C07D 471/04 (2006.01) C07D 207/12 (2006.01) C07D 317/28 (2006.01) C07D 407/04 (2006.01) C07D 487/04 (2006.01) C07D 493/04 (2006.01)

Patent

CA 2028076

07-27(635)A SYNTHESIS OF SWAINSONINE AND ANALOGS THEREOF Abstract of the Disclosure Swainsonine and analogs, namely, 1,4- dideoxy-1,4-imino-D-mannitol and the novel ring contracted swainsonines, (1S,2R,7R,7aR)-1,2-trihydroxypyrrolizidine and (1S,2R,7S,7aR)-1,2,7-trihydroxypyrrolizidine, are synthesized from the divergent intermediate, 4,5- anhydro-1-azido-1-deoxy-2,3-O-isopropylidene-D- talitol. These novel compounds are glycosidase inhibitors.

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