Dual curing silicone compositions

C - Chemistry – Metallurgy – 08 – L

Patent

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Details

C08L 83/06 (2006.01) C09D 183/06 (2006.01) H05K 3/28 (2006.01)

Patent

CA 2302685

The present invention relates to dual curing silicone compositions which are capable of crosslinking when subjected to actinic radiation and/or heat. The compositions contain a reactive organopolysiloxane having a functional group selected from the group consisting of (meth)acrylate, carboxylate, maleate, cinaminate and combinations thereof; a silicon hydride crosslinker; an organo- metallic hydrosilation catalyst; and a photoinitiator. These compositions can be cured to relatively thick films using UV light due to the presence of the specific olefinic unsaturated groups, and can also be partially or fully cured at room temperature or under thermal exposure. These compositions are particularly useful as conformal coatings, and in particular as coatings in electronic applications.

L'invention concerne des compositions à double processus de durcissement à base de silicone, qui sont capables de réticuler sous l'effet de la radiation actinique et/ou de la chaleur. Les compositions contiennent ce qui suit: un organopolysiloxane réactif qui possède un groupement fonctionnel sélectionné dans le groupe constitué de (méth)acrylate, de carboxylate, de maléate, de cinaminate et de leurs combinaisons; un agent réticulant hybride pour la silicone; un catalyseur organométallique d'hydrosilation; et un photoamorceur. On peut faire durcir ces compositions pour obtenir des films relativement épais, et ce au moyen de la lumière UV et grâce à la présence des groupes oléfiniques insaturés spécifiques. On peut également les faire durcir, complètement ou partiellement, en les laissant à température ambiante ou en les exposant à la chaleur. Ces compositions sont particulièrement utiles en tant que revêtements conformes, tout particulièrement en tant que revêtements destinés aux applications électroniques.

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