Process for the hydrogenation of sugars

C - Chemistry – Metallurgy – 07 – C

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C07C 31/26 (2006.01) A23L 1/09 (2006.01) A23L 1/236 (2006.01) C07C 29/141 (2006.01) C07C 31/18 (2006.01) C07H 15/04 (2006.01)

Patent

CA 2148755

The sugar alcohols mentioned as title compounds can be prepared from the corresponding sugars by catalytic hydrogenation in aqueous solution with hydrogen, the hydrogenation being carried out continuously at a hydrogen pressure of 100 to 400 bar and a reaction temperature of 40 to 80°C on support-free shaped bodies which are arranged in a fixed bed and are composed of pressed powders of alloys of the elements of the iron sub group of sub group VIII of the Periodic Table of the Elements containing elements of sub group VI. The shaped bodies have a compres- sive strength of 20 to 250 N and an internal surface area of 10 to 80 m2/g.

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