Process and apparatus for production of hydrogen using the...

C - Chemistry – Metallurgy – 01 – B

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C01B 3/16 (2006.01) C01B 3/12 (2006.01) B01J 7/00 (2006.01)

Patent

CA 2612814

A process and a reactor vessel for production of hydrogen via the water gas shift reaction at CO/CO2 ratios above 1.9, and steam to gas rations below 0.5, are disclosed. The process includes first reacting a feed gas mixture of carbon monoxide and steam in the presence of a precious metal catalyst on a structural support, yielding a resultant gas, and then reacting the resultant gas in the presence of a non-precious metal catalyst on a support medium. The reactor vessel includes a chamber having an inlet duct and an outlet. A structural support having the precious metal catalyst is positioned upstream of the non-precious metal catalyst positioned within the chamber. The structural support may be positioned within the inlet duct or within the chamber. The support medium may be a granular medium or a structural support.

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