C - Chemistry – Metallurgy – 07 – C
Patent
C - Chemistry, Metallurgy
07
C
C07C 255/20 (2006.01) C07B 31/00 (2006.01) C07B 41/02 (2006.01) C07C 253/30 (2006.01) C07C 255/21 (2006.01) C07D 207/34 (2006.01) C07D 207/416 (2006.01)
Patent
CA 2305618
An improved process for the preparation of cis-1,3-diols is described where a beta hydroxy ketone is treated with a trialkylborane or dialkylalkoxyborane or a mixture of a trialkylborane and a dialkylalkoxyborane followed by recovery and reuse of the alkylborane species to convert additional beta hydroxy ketone to the cis-1,3-diol.
Cette invention concerne un procédé amélioré de préparation de cis-1,3-diols, procédé dans lequel une cétone beta-hydroxy est traité à l'aide d'un trialkylborane ou d'un dialkylalcoxyborane ou, encore d'un mélange de trialkylborane et de dialkylalcoxyborane. L'espèce chimique alkylborane est ensuite récupérée puis réutilisée afin de transformer de la cétone beta-hydroxy additionnelle en cis-1,3-diol.
Bosch Robert Lee
Mccabe Richard Joseph
Nanninga Thomas Norman
Stahl Robert Joseph
Macrae & Co.
Warner-Lambert Company
Warner-Lambert Export Limited
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