Process for the selective hydrogenation of y, -epoxyalkenes...

Details Process for the selective hydrogenation of y, -epoxyalkenes... Process for the selective hydrogenation of y, -epoxyalkenes...

C - Chemistry, Metallurgy

07

D

C07D 303/04 (2006.01) C07C 45/58 (2006.01) C07D 301/00 (2006.01)

Patent

CA 2124947

Disclosed is a novel process for the preparation of epoxyalkanes and epoxycycloalkanes which comprises hydrogenating .gamma.,.delta.-epoxyalkenes or .gamma.,.delta.-epoxycycloalkenes in the presence of a rhodium catalyst. The process is especially useful for the preparation of 1,2-epoxybutane from 3,4-epoxy-1-butene.

On divulgue un nouveau procédé pour la préparation d'époxyalcanes et d'époxycycloalcanes qui comprend l'hydrogénation de gamma, delta-époxyalcènes ou de gamma, delta-époxycycloalcènes en présence d'un catalyseur de rhodium. Le procédé est particulièrement utile pour la préparation du 1,2-époxybutane à partir du 3,4-époxy-1-butène.

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