Method for producing anellated tetrahydro-[1h]-triazoles

C - Chemistry – Metallurgy – 07 – D

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C07D 498/04 (2006.01) A01N 43/90 (2006.01) C07C 331/28 (2006.01) C07D 249/00 (2006.01) C07D 273/00 (2006.01) C07D 275/04 (2006.01) C07D 413/12 (2006.01) C07D 417/12 (2006.01) C07D 513/04 (2006.01)

Patent

CA 2421839

The invention relates to a method for producing anellated tetrahydro-[1H]- triazoles of formula I wherein the variables Ra, Z, Z1, X, W, n and Q have the designations cited in patent claim 1, by cyclising compounds of general formula II wherein R represents C(X)OR2 or C(X)SR2, X represents oxygen or sulphur, and R2 has the designation cited in patent claim 1, in the presence of a base. The invention also relates to compounds of general formula I wherein W represents sulphur if Z represents a methylene group which is optionally substituted by Ra, as well as other compounds of formula I wherein Q represents a benzoxazole or benzothiazole radical. The invention further relates to the uses of said compounds as herbicides.

La présente invention concerne un procédé de préparation de tétrahydro-[1H]-triazoles de formule I, les variables R?a¿, Z, Z?1¿, X, W, n et Q ayant les significations spécifiées dans la revendication 1, par cyclisation de composés de formule générale II, R désignant C(X)OR?2¿ ou C(X)SR?2¿, X désignant oxygène ou soufre et R?2¿ ayant la signification spécifiée dans la revendication 1, en présence d'une base. L'invention concerne également des composés de formule générale I, W désignant soufre si Z désigne un groupe méthylène substitué le cas échéant par R?a¿, ainsi que d'autres composés de formule I, Q désignant un reste benzoxazole ou benzothiazole, et des utilisations de ces composés en tant qu'herbicides.

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