Tricyclic benzoylcyclohexanedione derivatives

C - Chemistry – Metallurgy – 07 – D

Patent

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C07D 495/04 (2006.01) A01N 43/90 (2006.01) C07D 231/00 (2006.01) C07D 239/00 (2006.01) C07D 261/00 (2006.01) C07D 311/00 (2006.01) C07D 335/00 (2006.01) C07D 498/04 (2006.01)

Patent

CA 2372241

The invention relates to tricyclic benzoylcyclohexanedione derivatives of formula (I), wherein the variables have the following meanings: X is oxygen, sulphur, S=O, S(=O)2, CR6R7, NR8 or a bond; y forms a saturated, partially saturated or unsaturated 5- or 6-membered heterocycle with the two carbons to which it is bonded; R1, R2, R6, R7 is hydrogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R3 is halogen, alkyl, alkyl halide, alkoxy or alkoxy halide; R4 is hydrogen, nitro, halogen, cyano, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, C1-C6- alkylthio halide, alkylsulfinyl, alkylsulfinyl halide, alkylsulfonyl, alkylsulfonyl halide, optionally substituted aminosulfonyl, or optionally substituted sulfonylamino; R5 is hydrogen, alkyl or halogen; m is 0, 1 or 2; R8 is hydrogen, alkyl, alkyl halide, alkylcarbonyl, formyl, alkoxycarbonyl, alkoxycarbonyl halide, alkylsulfonyl or alkylsulfonyl halide; and R9 is substituted (3-oxo-1-cyclohexen-2-yl)-carbonyl or substituted (1,3-dioxo-2-cyclohexyl)-methylidene; and to agriculturally useable salts thereof. The invention also relates to a method for producing the tricyclic benzoylcyclohexanedione derivatives, to products containing them and to the use of said derivatives or said products containing them for combating unwanted vegetation.

Dérivés tricycliques de benzoylcyclohexanediones de formule (I) dans laquelle X représente oxygène, soufre, S=O, S(=O)¿2?, CR?6¿R?7¿, NR?8¿ ou une liaison; Y forme avec les deux carbones auquel il est lié un hétérocycle à 5 ou 6 éléments saturé, partiellement saturé ou insaturé; R?1¿, R?2¿, R?6¿, R?7¿ représentent hydrogène, alkyle, halogénure d'alkyle, alcoxy ou halogénure d'alcoxy; R?3¿ représente halogène, alkyle, halogénure d'alkyle, alcoxy ou halogénure d'alcoxy; R?4¿ représente hydrogène, nitro, halogène, cyano, alkyle, halogénure d'alkyle, alcoxy, halogénure d'alcoxy, alkylthio, halogénure d'alkylthio C¿1?-C¿6?, alkylsulfinyle, halogénure d'alkylsulfinyle, alkylsulfonyle, halogénure d'alkylsulfonyle, aminosulfonyle éventuellement substitué, ou sulfonylamino éventuellement substitué; R?5¿ représente hydrogène, alkyle ou halogène; m vaut 0, 1 ou 2; R?8¿ représente hydrogène, alkyle, halogénure d'alkyle, alkylcarbonyle, formyle, alcoxycarbonyle, halogénure d'alcoxycarbonyle, alkylsulfonyle ou halogénure d'alkylsulfonyle; R?9¿ représente (3-oxo-1-cyclohexén-2-yl)-carbonyle substitué ou (1,3-dioxo-2-cyclohexyl)-méthylidène, ainsi que leurs sels utilisables en agriculture. La présente invention concerne également un procédé de préparation desdits dérivés tricycliques de benzoylcyclohexandiones, des produits qui contiennent ces dérivés, ainsi que l'utilisation de ces dérivés ou de produits les contenant pour lutter contre les plantes parasites.

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