Nickel-based dual catalyst systems effective in suppressing...

C - Chemistry – Metallurgy – 07 – D

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C07D 295/027 (2006.01) B01J 23/89 (2006.01) C07C 213/02 (2006.01) C07C 217/28 (2006.01) C07D 295/023 (2006.01)

Patent

CA 2058275

NICKEL-BASED DUAL CATALYST SYSTEMS EFFECTIVE SUPPRESSING CARBON DIOXIDE FORMATION DURING DIETHYLENE GLYCOL AMINATION (D#80,986-F) ABSTRACT OF THE DISCLOSURE Disclosed is a process for simultaneously producing morpholine and DIGLYCOLAMINE? amine while suppressing CO2 formation comprising the steps of: reacting anhydrous diethylene glycol with ammonia in the presence of added hydrogen over a dual nickel/ruthenium catalyst system comprising a nickel-based catalyst plus a supported ruthenium catalyst, and isolating said morpholine compound and said DIGLYCOLAMINE? amine compound from the reaction products. CLK:pg 80986.app

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