Process for the preparation of alkyl adipates

C - Chemistry – Metallurgy – 07 – C

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C07C 69/44 (2006.01) C07C 67/38 (2006.01)

Patent

CA 2083463

PRECIS DE LA DIVULGATION: La présente invention concerne un procédé de préparation d'adipates d'alkyle par réaction de l'oxyde de carbone et d'un alcool sur un pentènoate d'alkyle, sous pression supérieure à la pression atmosphérique et à température élevée, en présence d'une quantité catalytiquement efficace de cobalt ou d'un composé du cobalt et d'une base hétérocyclique azotée, caractérisé en ce qu'on engage à la réaction un mélange renfermant essentiellement du pentène-3 oate et du pentène-2 oate d'alkyle.

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