Process for the direct production of esters of carboxylic...

C - Chemistry – Metallurgy – 12 – P

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C12P 7/62 (2006.01) C07C 67/08 (2006.01) C07C 67/54 (2006.01) C12P 7/18 (2006.01) C12P 17/04 (2006.01)

Patent

CA 2657666

A process for producing an ester of carboxylic acid from a fermented broth is provided. The process comprises in one step providing a fermented broth containing at least one carboxylic acid salt. The following step comprises obtaining the ester of carboxylic acid by subjecting the carboxylic acid salt to an esterification in the presence of an alkanol under pressurized reactive distillation in the presence of CO2 as a catalyst. The process may further include a step wherein the ester of carboxylic acid is further subjected to a catalytic hydrogenation reaction, or a step wherein it is subjected to a catalytic oxidative dehydrogenation reaction.

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