Method and apparatus for vaporizing liquid chlorine...

C - Chemistry – Metallurgy – 01 – B

Patent

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C01B 7/075 (2006.01) C01B 21/083 (2006.01)

Patent

CA 2758368

A method of safely vaporizing liquid chlorine containing high concentrations of nitrogen trichloride contaminant from a chloralkali plant. In a vertical plug-flow vaporizer having an upward flow direction, a stream of liquid chlorine containing nitrogen trichloride is received. A gas such as air, nitrogen or chlorine gas is introduced into the liquid stream upstream of the boiling zone of the vaporizer to induce a flow regime, for example annular flow or mist flow, that prevents a mass accumulation of nitrogen trichloride in the vaporizer. The liquid chlorine containing nitrogen trichloride is vaporized. The resulting gas stream may be processed to destroy the nitrogen trichloride and recycled to the chlorine production train.

L'invention porte sur un procédé de vaporisation sans danger de chlore liquide contenant des concentrations élevées de contaminant trichlorure d'azote provenant d'une installation chlore/soude. Un vaporisateur à écoulement piston vertical ayant un sens de circulation vers le haut reçoit un flux de chlore liquide contenant du trichlorure d'azote. Un gaz tel que l'air, l'azote ou le chlore gazeux est introduit dans le flux de liquide en amont de la zone d'ébullition du vaporisateur pour provoquer un régime d'écoulement, par exemple un écoulement annulaire ou un écoulement en brouillard, qui empêche une accumulation massive de trichlorure d'azote dans le vaporisateur. Le chlore liquide contenant du trichlorure d'azote est vaporisé. Le flux de gaz ainsi obtenu peut être traité pour détruire le trichlorure d'azote et recyclé vers la chaîne de production de chlore.

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