Substituted isoquinoline derivatives and their use as...

C - Chemistry – Metallurgy – 07 – D

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C07D 217/04 (2006.01) A61K 31/47 (2006.01) C07D 217/02 (2006.01) C07D 217/06 (2006.01) C07D 401/12 (2006.01) C07D 405/12 (2006.01) C07D 409/12 (2006.01) C07D 413/12 (2006.01) C07D 417/12 (2006.01)

Patent

CA 2284218

Compounds of formula (I) and pharmaceutically acceptable salts thereof; where Q is a monocyclic or bicyclic aryl or heteroaryl ring, R1 is hydrogen, C1- 6alkyl (optionally substituted by hydroxy or C1-4alkoxy), C1-6alkenyl, C1- 6alkynyl, C1-6alkylCO-, formyl, CF3CO- or C1-6alkylSO2-, R2 is hydrogen or up to three substituents selected from halogen, NO2, CN, N3, CF3O-, CF3S-, CF3CO- , trifluoromethyldiazirinyl, C1-6alkyl, C1-6alkenyl, C1-6alkynyl, C1- 6perfluoroalkyl, C3-6cycloalkyl, C3-6cycloalkyl-C1-4alkyl-, C1-6alkylO-, C1- 6alkylCO-, C3-6cycloalkylO-, C3-6cycloalkylCO-, C3-6cycloalkyl-C1-4alkylO-, C3- 6cycloalkyl-C1-4alkylCO-, phenyl, phenoxy, benzyloxy, benzoyl, phenyl-C1- 4alkyl-, C1-6alkylS-, C1-6alkylSO2-, (C1-4alkyl)2NSO2-, (C1-4alkyl)NHSO2-, (C1- 4alkyl)2NCO-, (C1-4alkyl)NHCO- or CONH2; or -NR3R4 where R3 is hydroven or C1- 4alkyl, and R4 is hydrogen, C1-4alkyl, formyl, -CO2C1-4alkyl or -COC1-4alkyl; or two R2 groups together form a carbocyclic ring that is saturated or unsaturated and unsubstituted or substituted by -OH or =O; and X is hydrogen, halogen, C1-6alkoxy, C1-6alkyl, amino or trifluoroacetylamino, but when X is hydrogen excluding compounds in which R2 is 2-alkoxy and when X is hydrogen excluding the compounds N-(7-iodo-2-methyl-1,2,3,4-tetrahydroisoquinolin-5-yl) -5-benzoyl-2-methoxybenzamide, N-(7-iodo-1,2,3,4-tetrahydroisoquinolin-5-yl) - 5-benzoyl-2-methoxybenzamide, N-(5-iodo-1,2,3,4-tetrahydroisoquinolin-7-yl) -5- benzoyl-2-methoxybenzamide, N-(5-iodo-1,2,3,4-tetrahydroisoquinolin-7-yl) -2- methoxy-4-trifluoromethyldiazirinylbenzamide, N-(5-iodo-1,2,3,4- tetrahydroisoquinolin-7-yl) -2-methoxy-5-trifluoromethyldiazirinylbenzamide, N- (7-iodo-1,2,3,4,-tetrahydroisoquinolin-5-yl) -2-methoxy-5- trifluoromethyldiazirinylbenzamide et N-(8-fluoro-2-methyl-1,2,3,4- tetrahydroisoquinolin-5-yl) -4-t-butyl-2-methoxybenzamide, are useful inter alia in the treatment and prophylaxis of epilepsy.

Composés de la formule (I) et sels pharmaceutiquement acceptables de ces composés. Dans cette formule, Q représente un aryle monocyclique ou bicyclique ou un noyau hétéroaryle; R?1¿ représente de l'hydrogène, un C¿1-6?alkyle (éventuellement substitué par un hydroxy ou un C¿1-4?alkoxy), un C¿1-6?alcényle, un C¿1-6?alkynyle, un C¿1-6?alkylCO-, un formyle, un CF¿3?CO- ou un C¿1-6?alkylSO¿2?-, R?2¿ représente de l'hydrogène ou jusqu'à trois substituants sélectionnés à partir d'un halogène, de NO¿2?, CN, N¿3?, CF¿3?O-, CF¿3?S-, CF¿3?CO-, de trifluorométhyldiazirinyle, C¿1-6?alkyle, C¿1-6?alcényle, C¿1-6?alkynyle, C¿1-6?perfluoroalkyle, C¿3-6?cycloalkyle, C¿3-6?cycloalkyl-C¿1-4?alkyl-, C¿1-6?alkylO-, C¿1-6?alkylCO-, C¿3-6?cycloalkylO-, C¿3-6?cycloalkylCO-, C¿3-6?cycloalkyl-C¿1-4?alkylO-, C¿3-6?cycloalkyl-C¿1-4?alkylCO-, phényle, phénoxy, benzyloxy, benzoyle, phényl-C¿1-4?alkyl-, C¿1-6?alkylS-, C¿1-6?alkylSO¿2?-, (C¿1-4?alkyl)¿2?NSO¿2-?, (C¿1-4?alkyl)NHSO¿2?-, (C¿1-4?alkyl)¿2?NCO-, (C¿1-4?alkyl)NHCO- ou CONH¿2?; ou bien -NR?3¿R?4¿ où R?3¿ représente de l'hydrogène ou C¿1-4?alkyl et R?4¿ représente de l'hydrogène, C¿1-4?alkyle, formyle, -CO¿2?C¿1-4?alkyle ou -COC¿1-4?alkyle; ou bien deux groupes R?2¿ forment ensemble un noyau carbocyclique qui est saturé ou non et substitué ou non par -OH ou =OH; et X représente de l'hydrogène, halogène, C¿1-6?alkoxy, C¿1-6?alkyle, amino ou trifluoroacétylamino; mais lorsque X représente de l'hydrogène, cela exclue les composés dans lesquels R?2¿ représente 2-alkoxy et lorsque X représente de l'halogène, cela exclue les composés N-(7-iodo-2-méthyl-1,2,3,4-tétrahydroisoquinolin-5-yl) -5-benzoyl-2-méthoxybenzamide, N-(7-iodo-1,2,3,4-tétrahydroisoquinolin-5-yl) -5-benzoyl-2-méthoxybenzamide, N-(5-iodo-1,2,3,4-tétrahydroisoquinolin-7-yl) -5-benzoyl-2-méthoxybenzamide, N-(5-iodo-1,2,3,4-tétrahydroisoquinolin-7-yl) -2-méthoxy-4-trifluorométhyldiazirinylbenzamide, N-(5-iodo-1,2,3,4-tétrahydroisoquinolin-7-yl) -2-méthoxy-5-trifluorométhyldiazirinylbenzamide, N-(7-iodo-1,2,3,4,-tétrahydroisoquinolin-5-yl) -2-méthoxy-5-trifluorométhyldiazirinylbenzamide et N-(8-fluoro-2-méthyl-1,2,3,4-tétrahydroisoquinolin-5-yl) -4-t-butyl-2-méthoxybenzamide. Ces composés sont utilisés, entre autres choses, dans le traitement et la prophylaxie de l'épilepsie.

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