Process for isomerizing endo-form of aromatic...

C - Chemistry – Metallurgy – 07 – C

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C07C 13/28 (2006.01) C07C 5/22 (2006.01) C07C 25/22 (2006.01) C07C 43/215 (2006.01) C08F 210/02 (2006.01) C08F 232/08 (2006.01)

Patent

CA 2061003

A process for isomerization of an endo-form of aromatic group-containing norbornenes represented by the following formula (I) to an exo-form which comprises bringing the endo-form into contact with a solid acid catalyst. Image wherein p is 0 or an integer of 1 or more, q and r are each 0,1 or 2, R1 to R15 are each independently hydrogen or halogen atom, aliphatic hydrocarbon group, aromatic hydrocarbon group or alkoxy group, R5 (or R6) are R9 (or R7) may be linked together through an alkylene group of 1-3 carbons or may be directly linked together.

Divulgation d'un procédé pour l'isomérisation, d'une forme endo en une forme exo, de norbornènes contenant des groupes aromatiques, représentés par la formule suivante (I) Image , dans laquelle : p est un entier; q et r sont chacun égaux à 0, 1 ou 2; R1 à R15 représentent chacun, de manière indépendante, un atome d'hydrogène ou d'halogène, un groupement aliphatique hydrocarboné, un groupement aromatique hydrocarboné ou un groupement alcoxy; R5 (ou R6) et R9 (ou R7) peuvent être reliés directement ou par l'intermédiaire d'un groupement alkylène en C1-C3. Ce procédé comprend la mise en contact de la forme endo avec un catalyseur solide acide.

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