Thrombin derivative and pharmaceutical composition...

C - Chemistry – Metallurgy – 12 – N

Patent

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C12N 9/74 (2006.01) A61K 38/55 (2006.01) A61P 7/00 (2006.01) A61P 29/00 (2006.01) C12N 15/12 (2006.01)

Patent

CA 2560247

It is intended to provide a thrombin derivative comprising A and B chains wherein the B chain has an amino acid sequence derived from the amino acid sequence of thrombin B chain by the substitution at one or more active center amino acids selected from among serine at the 205-position, glycine at the 203- position, aspartic acid at the 99-position and histidine at the 43-position, and (1) in the case of reacting with a thrombin substrate at 37oC for 3 hours in a 50 mM tris hydrochloride buffer (pH 7.4) containing 0.1 M of NaCl, the ratio of the thrombin substrate decomposed by the thrombin derivative being 10% or lower; and (2) sustaining the structure of exocite I.

La présente invention vise à fournir un dérivé de thrombine comportant des chaînes A et B, ladite chaîne B comprenant une séquence d'acides aminés dérivée de la séquence d'acides aminés de la chaîne B de la thrombine par la substitution au niveau d'une ou de plusieurs acides aminés centraux choisis parmi la sérine à la position 205, la glycine à la position 203, l'acide aspartique à la position 99 et l'histidine à la position 43 ; et (1) dans le cas d'une réaction avec un substrat à base de thrombine à 37 °C pendant 3 heures dans 50 mM de solution tampon de tris-chlorhydrate (pH 7,4) contenant 0,1 M de NaCl, le rapport du substrat de thrombine décomposé par le dérivé de thrombine étant égal ou inférieur à 10 % ; et (2) la préservation de la structure d'exocite I.

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