Process for making hydroxy-terminated aromatic oligomeric...

C - Chemistry – Metallurgy – 07 – F

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C07F 9/12 (2006.01)

Patent

CA 2206130

The present invention is a process for forming hydroxy-terminated aromatic oligomeric phosphates by the initial reaction of a monoaryl dihalophosphate, such as monophenyl dichlorophosphate, with an aromatic diol, such as resorcinol, to form a halo-terminated aromatic oligomeric phosphate and the subsequent reaction of that halo-terminated phosphate with aromatic diol to form the hydroxy-terminated aromatic oligomeric phosphate. The initial and subsequent reactions preferably employ a Lewis acid catalyst, such as magnesium dichloride.

La présente invention concerne un procédé de formation de phosphates oligomères aromatiques à terminaison hydroxy. Ce procédé consiste à mettre initialement en réaction un monoaryle dihalophosphate tel que le monophényle dichlorophosphate avec un diol aromatique tel que le résorcinol, cette réaction initiale donnant alors un phosphate oligomère aromatique à terminaison halo. Le procédé consiste ensuite à mettre en réaction ce phosphate oligomère aromatique à terminaison halo avec un diol aromatique, cette dernière réaction donnant alors un phosphate oligomère aromatique à terminaison hydroxy. La réaction initiale et la dernière réaction se font de préférence en préférence d'un catalyseur à base d'un acide de Lewis tel que le dichlorure de magnésium.

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