Process for the production of organosilsesquioxanes

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 77/06 (2006.01) C08G 77/14 (2006.01) C08G 77/20 (2006.01) C08G 77/26 (2006.01) C08G 77/58 (2006.01) C08L 83/04 (2006.01) C09D 183/04 (2006.01) C09D 183/06 (2006.01) C09J 183/04 (2006.01) C09J 183/06 (2006.01)

Patent

CA 2632254

A process for forming a composition comprising organosilsesguioxanes, comprises the following steps: 1. partially hydrolysing hydrolysable inorganic monomer precursors comprising at least 50 mole% of first hydrolysable inorganic monomer precursors having the formula RSiY3, in which R is an organic group, the R-Si bond is a non-hydrolysable bond, each Y group is the same as or different to one another and is selected from chemically-reactive groups such that each Si-Y bond is hydrolysable to form a Si-OH bond, to form inorganic monomers and allowing partial condensation of the inorganic monomers to form a liquid composition comprising inorganic oligomers; 2. prior to complete condensation of the inorganic monomers, quenching the liquid composition with an amount of water which, in combination with the water used in step (1) and any water liberated by condensation of the inorganic monomers in step (1) , is in excess of the stoichiometric amount of water required to achieve complete hydrolysis of all the hydrolysable inorganic monomer precursors present; and 3. drying the composition.

L~invention concerne un procédé de fabrication d~une composition comprenant des organosilsesquioxanes, ledit procédé comprenant les étapes suivantes : 1. hydrolyser en partie des précurseurs de monomères inorganiques hydrolysables comprenant au moins 50 % en moles de premiers précurseurs de monomères inorganiques hydrolysables de formule RSiY3, dans laquelle R représente un groupe organique, la liaison R-Si est une liaison non hydrolysable, chaque groupement Y est identique ou différent et est choisi parmi des groupements chimiquement réactifs de manière à ce que chaque liaison Si-Y soit hydrolysable pour former une liaison Si-OH, afin de former des monomères inorganiques et permettre la condensation partielle des monomères inorganiques afin de former une composition liquide comprenant des oligomères inorganiques ; 2. avant la condensation totale des monomères inorganiques, refroidir rapidement la composition liquide avec une quantité d~eau qui, mélangée à l~eau utilisée à l~étape (1), est en excès par rapport à la quantité stoechiométrique d~eau nécessaire pour réaliser l~hydrolyse totale de tous les précurseurs de monomères inorganiques hydrolysables présents ; et 3. sécher la composition.

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