Regeneration of a working solution in a hydrogen peroxide...

C - Chemistry – Metallurgy – 07 – C

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C07C 46/10 (2006.01) B01J 19/12 (2006.01) C01B 15/023 (2006.01) C07C 46/00 (2006.01) C07C 50/18 (2006.01)

Patent

CA 2402156

The invention relates to a method of regenerating hydrogenated and/or oxygenated alkyl anthraquinones and/or alkyl anthrahydroquinones to alkyl anthraquinones and/or alkyl anthrahydroquinones, wherein the reaction is carried out in the presence of a catalyst under electromagnetic irradiation. Additionally the invention relates to a method for regenerating a working solution containing hydrogenation and/or oxidation products of alkyl anthraquinones and/or alkyl anthrahydroquinones dissolved in at least one solvent, wherein said working solution contains alkyl anthraquinone and/or alkyl anthrahydroquinone products being formed during the production of hydrogen peroxide by a cyclic process including alternate reduction and oxidation of the working solution, said method comprising contacting the working solution containing hydrogenation and/or oxidation products of alkyl anthraquinones and/or alkyl anthrahydroquinones with a catalyst under electromagnetic irradiation to convert the hydrogenation and/or oxidation products of alkyl anthraquinones and/or alkyl anthrahydroquinones to productive alkyl anthraquinones and/or alkyl anthrahydroquinones.

L'invention concerne un procédé de régénération d'anthraquinones alkylées hydrogénées et/ou oxygénées et/ou d'anthrahydroquinones alkylées pour obtenir des anthraquinones alkylées et/ou des anthrahydroquinones alkylées. Dans ce procédé, la réaction est mise en oeuvre en présence d'un catalyseur dans des conditions d'irradiation électromagnétique. De plus, l'invention concerne un procédé de régénération d'une solution active contenant des produits d'hydrogénation et/ou d'oxydation d'anthraquinones alkylées et/ou d'anthrahydroquinones alkylées dissous dans au moins un solvant ; la solution active contient des produits d'anthraquinone alkylée et/ou d'anthrahydroquinone alkylée formés au cours de la production de peroxyde d'hydrogène à l'aide d'un procédé cyclique comprenant une réduction et une oxydation alternées de la solution active. Le procédé comporte la mise en contact de la solution active contenant des produits d'hydrogénation et/ou d'oxydation d'anthraquinones alkylées et/ou d'anthrahydroquinones alkylées à l'aide d'un catalyseur dans des conditions d'irradiation électromagnétique pour transformer les produits d'hydrogénation et/ou d'oxydation d'anthraquinones alkylées et/ou d'anthrahydroquinones alkylées en anthraquinones alkylées et/ou en anthrahydroquinones alkylées exploitables.

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