Removal of hydrogen sulfide from fluid streams with minimum...

B - Operations – Transporting – 01 – D

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B01D 53/14 (2006.01) B01D 53/34 (2006.01) C01B 17/60 (2006.01) C01B 17/62 (2006.01)

Patent

CA 2001890

ABSTRACT Fluid streams containing hydrogen sulfide such as a geothermal steam or a sour gas stream are contacted with an aqueous solution of a polyvalent metal chelate and a bisulfite whereby the hydrogen sulfide is converted to free sulfur and then to soluble sulfur compounds. The metal chelate is reduced to a lower oxidation state metal chelate and reduced metal chelate is subsequently oxidized with air back to the higher oxidation state and reused. The bisulfite is formed by combustion of a hydrogen sulfide portion of the fluid stream and subsequent absorption of the sulfur dioxide formed thereby in a two-stage countercurrent scrubber operating at conditions favorable for high bisulfite and low sulfite formation and selective away from carbon dioxide absorption.

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