Process for the preparation of an optically acitive...

C - Chemistry – Metallurgy – 12 – P

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C12P 17/10 (2006.01) C12P 41/00 (2006.01)

Patent

CA 2580151

The present disclosure provides enzymatic methods for generating stereoisomerically pure products by resolving a racemic mixture of N-protected .beta.-lactams with a lipase from Candida antarcticawith high stereospecificity. The presence of a carbamate protecting group, such as the tert-butoxycarbonyl group protecting group, on the (3-lactam enhances enzyme catalysis and stereoselectivity.

La présente invention concerne des procédés enzymatiques permettant de générer des produits stéréoïsomériquement purs par résolution d'un mélange racémique de ß-lactams N-protégés avec une lipase issue de Candida antarctica de haute stéréospécificité. La présence d'un groupe protecteur carbamate, et notamment tert-butoxycarbonyle, sur le ß-lactam renforce la catalyse et la stéréosélectivité des enzymes.

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