Rejuvenating sapo and/or alpo molecular sieve with anhydrous...

B - Operations – Transporting – 01 – J

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B01J 29/04 (2006.01) B01J 29/85 (2006.01) B01J 29/90 (2006.01) B01J 38/50 (2006.01) B01J 38/52 (2006.01) C07C 1/20 (2006.01)

Patent

CA 2401710

Disclosed is a method of rejuvenating a molecular sieve. The method includes contacting a molecular sieve having a methanol uptake of less than 1, or a catalyst containing molecular sieve having a methanol up of less than 1, with anhydrous liquid or vapor until the methanol uptake ratio is increased by at least 10 %. The rejuvenated molecular sieve or catalyst can be used to make an olefin product from an oxygenate-containing feedstock. The preferred molecular sieves silicoaluminophosphate (SAPO) and/or aluminophosphate molecular sieves.

L'invention se rapporte à un procédé de régénération d'un tamis moléculaire. Ledit procédé consiste à mettre en contact un tamis moléculaire ayant un indice d'absorption du méthanol inférieur à 1, ou un catalyseur contenant un tamis moléculaire ayant un indice d'absorption du méthanol inférieur à 1, avec un liquide ou une vapeur anhydre jusqu'à ce que l'indice d'absorption du méthanol soit accru d'au moins 10 %. Le tamis moléculaire ou catalyseur régénéré peut être utilisé pour fabriquer un produit oléfinique à partir d'une charge d'alimentation contenant un composé oxygéné. Les tamis moléculaires préférés sont les tamis moléculaires à base de silicoaluminophosphates (SAPO) et ou d'aluminophosphates.

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