Fluorinated beta-ketoiminato metal complexes

Details Fluorinated beta-ketoiminato metal complexes Fluorinated beta-ketoiminato metal complexes

C - Chemistry, Metallurgy

07

F

260/428

C07F 1/08 (2006.01) C07C 251/06 (2006.01) C07F 15/06 (2006.01) C23C 16/18 (2006.01)

Patent

CA 2037538

ABSTRACT Fluorinated .beta.-ketoimine ligands and highly volatile .beta.-ketoiminato metal complexes of the ligands are synthesized by silylatlng a fluorinated .beta.-dike- tone to form a sllylenolether, and subsequently reacting the silylenolether with a primary diamine to form the desired ligand having the structural formula: Image wherein R1, R2, R4 and R5 are independently linear or branched per- fluorinated, C1-C8 alkyl groups and R3 is any organic functionality such as a C1-C8 alkylene, phenylene or hydroxyalkylene group, all of which can be partially or fully fluorinated. The corresponding metal complex is formed by treatlng the ligand with a metal halide.

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