Process for the production of a porous cross-linked...

C - Chemistry – Metallurgy – 08 – B

Patent

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C08B 37/00 (2006.01) B01D 15/08 (2006.01) B01J 20/22 (2006.01) B01J 20/291 (2006.01) C08B 37/12 (2006.01)

Patent

CA 2251050

A process for the production of a porous cross-linked polysaccharide gel and a gel obtainable by the following steps: a) preparing a solution or dispersion of the polysaccharide; b) adding a bifunctional cross- linking agent having one active site and one inactive site to the solution or dispersion from step a); c) reacting hydroxylgroups of the polysaccharide with the active site of the cross-linking agent; d) forming a polysaccharide gel; e) activating the inactive site of the cross- linking agent; f) reacting the activated site from step e) with hydroxylgroups of the polysaccharide gel, whereby cross-linking of the gel takes place. The cross-linked polysaccharide gel obtained can further be cross-linked by conventional methods, one or several times.

L'invention concerne un procédé permettant de produire un gel polysaccharidique réticulé poreux, ainsi qu'un gel pouvant être obtenu par les étapes suivantes: a) on prépare une solution ou une dispersion du polysaccharide; b) on ajoute à la solution ou à la dispersion de l'étape (a) un agent de réticulation bifonctionnel ayant un site actif et un site inactif; c) on fait réagir des groupes hydroxyles du polysaccharide avec le site actif de l'agent de réticulation; d) on forme un gel polysaccharidique; e) on active le site inactif de l'agent de réticulation; f) on fait réagir le site activé de l'étape (e) avec des groupes hydroxyles du gel polysaccharidique, ce qui entraîne la réticulation du gel. On peut continuer à réticuler le gel polysaccharidique réticulé obtenu par des procédés conventionnels, une ou plusieurs fois.

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