Processes for the preparation polyolefin resins using...

C - Chemistry – Metallurgy – 08 – F

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C08F 10/00 (2006.01) C08F 4/02 (2006.01) C08F 4/643 (2006.01) H01G 4/18 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2393327

This invention relates to olefin polymerization processes suitable for limiting or eliminating aromatic solvents or diluents. The invention processes can be conducted by contacting polymerizable olefin monomers with catalyst complexes of Group 3-11 metal cations and noncoordinating or weakly coordinating anions bound directly to the surfaces of finely divided substrate particles or to polymer chains capable of effective suspension or solvation in polymerization solvents or diluents under polmerization conditions. These processes minimize problems associated with using largely insoluble organometallic or organometalloid catalysts and cocatalysts in aliphatic, solution, or diluent polymerization processes.

L'invention concerne des procédés de polymérisation d'oléfines appropriés à la limitation ou à l'élimination de diluants ou de solvants aromatiques, que l'on peut conduire par contact entre des monomères d'oléfines polymérisables et des complexes catalyseurs de cations métalliques (groupe 3-11), avec coordination nulle ou faible des anions liés directement aux surfaces des particules de substrat finement divisées ou aux chaînes polymères capables de solvatation ou de suspension effective dans des solvants ou des diluants de polymérisation, en conditions de polymérisation. Les procédés considérés permettent de réduire au minimum les difficultés associées à l'utilisation de catalyseurs et cocatalyseurs organométalliques ou organométalloïdes insolubles dans les procédés de polymérisation de type aliphatique, en solution ou par diluant.

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