Photochromic indeno-fused naphthopyrans

C - Chemistry – Metallurgy – 07 – D

Patent

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C07D 295/096 (2006.01) C07C 215/68 (2006.01) C07D 207/04 (2006.01) C07D 211/08 (2006.01) C07D 241/04 (2006.01) C09K 9/02 (2006.01) G02B 5/23 (2006.01)

Patent

CA 2631854

Photochromic materials comprising indeno- fused naphthopyrans having substituents comprising a 4-fluorcVhenyl group and a 4-aminophenyl group bonded to the 3- position of the indeno- fused naphthopyran are disclosed. The photochromic materials may exhibit faster fade rates as compared to similar indeno-fiised naphthopyrans without a 4- fluorophenyl group and a 4- aminophenyl group bonded to the 3-position of the indeno-fiised naphthopyran. Substituted 2-propyn-l-ols utilized for the synthesis of the indeno-fused naphthopyrans disclosed herein are disclosed. Photochromic compositions and articles, such as optical elements, incorporating the photochromic materials disclosed herein are also disclosed.

L'invention concerne des matières photochromiques comprenant des naphthopyranes indénofusionnés qui présentent des substituants comprenant un groupe 4-fluorophényle et un groupe 4-aminophényle reliés à la position 3 du naphthopyrane indénofusionné. Les matières photochromiques peuvent présenter des taux de décoloration plus rapides que les taux de décoloration de naphthopyranes indénofusionnés analogues ne présentant pas l'ensemble comprenant le groupe 4- fluorophényle et le groupe 4-aminophényle reliés à la position 3 du naphthopyrane indénofusionné. Des 2-propyn-1-ols substitués, utilisés pour la synthèse des naphthopyranes indénofusionnés de l'invention, sont décrits dans la description. Des compositions et des articles photochromiques, notamment des éléments optiques intégrant les matières photochromiques de l'invention, sont également décrits dans la description.

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