Measurement of distributed total acid numbers of a...

G - Physics – 01 – N

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G01N 24/00 (2006.01) G01N 33/24 (2006.01)

Patent

CA 2618318

The present invention is a method to determine the TAN and TAN as a function of boiling point for a hydrocarbon feedstream using an electrospray ionization mass spectrometer (ESI-MS). The steps of the method include determining the signal as a function of mass from the ESI-MS while minimizing the formation of oligomers and fragmentation of the molecular species in the feedstream and then determining the TAN from the signals. The TAN is also determined as a function of boiling point.

L'invention concerne un procédé de détermination de TAN, et de TAN en fonction du point d'ébullition dans un courant d'alimentation d'hydrocarbure, par spectrométrie de masse avec ionisation par électronébulisation (ESI-MS). Les étapes du procédé comprennent la détermination du signal en fonction de la masse, à partir de ESI-MS, tout en minimisant la formation d'oligomères et la fragmentation des espèces moléculaires dans le courant d'alimentation, puis la détermination de TAN à partir des signaux. Le TAN est également déterminé en fonction du point d'ébullition.

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