Catalysis of cycloalkenes to saturated polycyclic oligomers

Details Catalysis of cycloalkenes to saturated polycyclic oligomers Catalysis of cycloalkenes to saturated polycyclic oligomers

C - Chemistry, Metallurgy

08

F

C08F 4/69 (2006.01) C08F 132/04 (2006.01) C08F 132/08 (2006.01) C08G 61/08 (2006.01)

Patent

CA 2284237

The invention relates to a homogeneous two-component catalyst system consisting of (a) a salt of a transition metal selected from the Group VIb of the Periodic Table; and (b) an organosilicon compound having the formula: R x Si(OR')y(OSiR3)z (Ia) (R2SiO)3 ~~(Ib) or ~(R3Si)2NH ~~(Ic) wherein R is identical or different and represents a hydrogen atom, a C1-C4 alkyl or phenyl group; R' represents a C1-C4 alkyl or phenyl group; 0 < x <= 3; 0 <= y < 4; z=0 or 1; y+z <= 1; x+y+z=4; and wherein the molar ratio of component (b) to component (a) is at least about 0.5:1. Such a catalyst system is useful for the catalysis of cycloalkenes to saturated polycyclic oligomers.

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