Method of treating shale and clay in hydrocarbon formation...

E - Fixed Constructions – 21 – B

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E21B 43/25 (2006.01) C09K 8/035 (2006.01) C09K 8/10 (2006.01) C09K 8/24 (2006.01) C09K 8/60 (2006.01)

Patent

CA 2151152

Swelling and migration of subterranean clay is inhibited during drilling for and stimulation of the production of hydrocarbon fluids, and preparation therefor, by treating said formations with a copolymer of about 5 % to about 50 % of an anionic monomer such as acrylic acid, methacrylic acid, or 2- acrylamido-2-methyl propane sulfonic acid and the balance a cationic monomer selected from dimethyl diallyl ammonium chloride, or acryloxy or methacryloxy ethyl, propyl or 3-methyl butyl trimetyl ammonium chlorides or methosulfates. Permeability damage to the formation is reduced in the presence of the copolymer; it is particularly effective in spite of the presence of a foaming agent.

On empêche le gonflement et la migration d'argile souterraine pendant le forage et pour la stimulation de la production de fluides hydrocarbures, ainsi que leur préparation, en traitant lesdites formations à l'aide d'un copolymère d'environ 5 % à environ 50 % d'un monomère anionique tel que l'acide acrylique, l'acide métacrylique, ou l'acide 2-acrylamido-2-méthyle propane sulfonique, le solde étant constitué d'un monomère cationique choisi entre le chlorure de diméthyle diallyle ammonium, l'acryloxy éthyle ou le méthacryloxy éthyle, des chlorures ou des méthosulfates de propyle ou 3-méthyle butyle triméthyle ammonium. Les détériorations de la formation dues à la perméabilité sont réduites en présence du copolymère, il est particulièrement efficace malgré la présence d'un agent moussant.

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