Process for olefin isomerization

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 5/23 (2006.01) C07C 5/25 (2006.01)

Patent

CA 2271048

A process for the double bond isomerization of olefinic feed compounds is provided comprising contacting the olefinic feed compounds and a catalyst under reaction conditions sufficient to produce double bond isomerization, wherein the catalyst is an aluminophosphate-containing molecular sieve with pores having a diameter in the range of about 3.8 .ANG. to about 5 .ANG.. The process provides high conversion of normal alpha-olefins and high selectivity for linear internal olefins.

Cette invention se rapporte à un procédé d'isomérisation à double liaison de composés de départ oléfiniques, qui consiste à mettre en contact des composés de départ oléfiniques et un catalyseur dans des conditions réactionnelles suffisantes pour produire une isomérisation à double liaison, ledit catalyseur étant un tamis moléculaire contenant des aluminophosphates et doté de pores ayant un diamètre compris entre 3,8 .ANG. environ et 5 .ANG. environ. Ledit procédé assure une conversion élevée d'alpha-oléfines normales et une forte sélectivité s'agissant de l'obtention d'oléfines internes linéaires.

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