Process for controlled radical polymerization in aqueous...

C - Chemistry – Metallurgy – 08 – F

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C08F 2/38 (2006.01) C08F 4/00 (2006.01) C08F 293/00 (2006.01)

Patent

CA 2422058

The present invention relates to a process for controlled radicalpolymerization in aqueous dispersion in the presence of selected nitroxyl radicals having a defined partition equilibrium between water and monomer as measured by their log p. wherein p is the partition coefficient of the nitroxyl radical in octanol and water.

L'invention concerne une méthode de polymérisation radicalaire contrôlée dans une dispersion aqueuse en présence de radicaux de nitroxyle sélectionnés présentant un coefficient de partage défini entre l'eau et un monomère tel que mesuré par leur Log P. P étant le coefficient de partage octanol/eau du radical de nitroxyle.

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