Monolithic alpha-alumina articles having controlled...

C - Chemistry – Metallurgy – 04 – B

Patent

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C04B 35/111 (2006.01) C04B 35/624 (2006.01)

Patent

CA 2392136

Disclosed is a sol-gel process for making high-density monolithic alpha- alumina articles. Cracking problems caused by shrinkage of the gel during the drying and firing stages are minimized by controlling the temperature and humidity during the drying process and by using molds formed of prescribed polymeric materials, preliminarly coated with a silicone release agent. The process of the invention provides porous alpha-alumina articles having a controlled microstructure and a controlled pore size distribution, which are beneficial features when the material is used in practical applications, e.g., as substrates for gas sensors.

L'invention concerne un procédé sol-gel destiné à la fabrication d'articles d'alpha-alumine monolithiques à densité élevée. Les problèmes de craquelures liés au retrait du gel pendant les étapes de séchage et de cuisson sont minimisés par régulation de la température et de l'humidité au cours du processus de séchage et par utilisation de moules constitués de matières polymériques spécifiques préalablement revêtus d'un agent de démoulage de silicone. Le procédé de l'invention permet d'obtenir des articles d'alpha-alumine poreux présentant une répartition de dimension des pores ainsi qu'une microstructure contrôlées. Ces caractéristiques sont avantageuses lorsque cette matière est utilisée dans des applications pratiques, notamment comme substrat pour détecteurs de gaz.

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